1-[1,4-Bis(but-3-en-1-yloxy)]-2,3,4,5-(1,4-dimethoxy)pillar[5]arene–1,4-dibromobutane 1:1 inclusion complex
نویسندگان
چکیده
In the title compound, C 51 H 58 O 10 ·C 4 8 Br 2 , both host and guest are completed by crystallographic twofold symmetry (one carbon atom of lies on rotation axis). The pentagonal-shaped macrocycle has a pair buteneoxy substituents one its faces molecule 1,4-dibromobutane is encapsulated within cavity pillararene, forming 1:1 inclusion complex. terminal alkene parts, which project outwards from pillararene ring, exhibit positional disorder over two sets sites in 0.52 (2): 0.48 (2) ratio. interact via C—H...O, C—H...Br C—H...π interactions adjacent molecules C—H...O bonds.
منابع مشابه
ABSTRACTS IN PERSIAN Vol.14, No.1
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ژورنال
عنوان ژورنال: IUCrData
سال: 2023
ISSN: ['2414-3146']
DOI: https://doi.org/10.1107/s2414314623005886